Interfacial electrodeposition of silver

L. Zeiri, O. Younes, S. Efrima, M. Deutsch

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

A systematic study of silver ion electrodeposition at the water/air and water/dichloromethane interfaces, under potentiostatic control, is presented. We study the morphology of the deposits and their growth rate, as a function of several important physical and chemical parameters, namely, the electric voltage, the silver ion concentration, the conductivity, the viscosity, and the presence of a surfactant and an organic anionic additive known to associate with silver. The results are discussed in terms of a generalized Wagner number, which is shown to correlate well with the observations and to be a highly reliable predictive tool for the morphologies.

Original languageEnglish
Pages (from-to)9299-9308
Number of pages10
JournalJournal of Physical Chemistry B
Volume101
Issue number45
DOIs
StatePublished - 6 Nov 1997

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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