Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid

I. D. Kalikhman, N. A. Kryukova, V. A. Pestunovich, N. I. Ivanova, S. V. Amosova, B. A. Trofimov

Research output: Contribution to journalArticlepeer-review


The method of a complete analysis of the shape of the lines was used to determine the activation parameters of hindered rotation around the N-C bond in the molecules of N,N-dimethyldithiocarbamic acid esters. The value of the barrier in these compounds is lower than in the thioamides, and depends on the electronic and steric nature of the substituent on the sulfur atom.

Original languageEnglish
Pages (from-to)1332-1334
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Issue number6
StatePublished - 1 Jun 1976
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry


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