Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid

I. D. Kalikhman; N. A. Kryukova; V. A. Pestunovich; N. I. Ivanova; S. V. Amosova; B. A. Trofimov

doi:10.1007/BF00928087

Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid

I. D. Kalikhman, N. A. Kryukova, V. A. Pestunovich, N. I. Ivanova, S. V. Amosova, B. A. Trofimov

Research output: Contribution to journal › Article › peer-review

Abstract

The method of a complete analysis of the shape of the lines was used to determine the activation parameters of hindered rotation around the N-C bond in the molecules of N,N-dimethyldithiocarbamic acid esters. The value of the barrier in these compounds is lower than in the thioamides, and depends on the electronic and steric nature of the substituent on the sulfur atom.

Original language	English
Pages (from-to)	1332-1334
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	25
Issue number	6
DOIs	https://doi.org/10.1007/BF00928087
State	Published - 1 Jan 1976
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00928087

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title = "Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid",

abstract = "The method of a complete analysis of the shape of the lines was used to determine the activation parameters of hindered rotation around the N-C bond in the molecules of N,N-dimethyldithiocarbamic acid esters. The value of the barrier in these compounds is lower than in the thioamides, and depends on the electronic and steric nature of the substituent on the sulfur atom.",

author = "Kalikhman, \{I. D.\} and Kryukova, \{N. A.\} and Pestunovich, \{V. A.\} and Ivanova, \{N. I.\} and Amosova, \{S. V.\} and Trofimov, \{B. A.\}",

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doi = "10.1007/BF00928087",

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T1 - Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid

AU - Kalikhman, I. D.

AU - Kryukova, N. A.

AU - Pestunovich, V. A.

AU - Ivanova, N. I.

AU - Amosova, S. V.

AU - Trofimov, B. A.

PY - 1976/1/1

Y1 - 1976/1/1

N2 - The method of a complete analysis of the shape of the lines was used to determine the activation parameters of hindered rotation around the N-C bond in the molecules of N,N-dimethyldithiocarbamic acid esters. The value of the barrier in these compounds is lower than in the thioamides, and depends on the electronic and steric nature of the substituent on the sulfur atom.

AB - The method of a complete analysis of the shape of the lines was used to determine the activation parameters of hindered rotation around the N-C bond in the molecules of N,N-dimethyldithiocarbamic acid esters. The value of the barrier in these compounds is lower than in the thioamides, and depends on the electronic and steric nature of the substituent on the sulfur atom.

UR - https://www.scopus.com/pages/publications/34250292819

U2 - 10.1007/BF00928087

DO - 10.1007/BF00928087

M3 - Article

AN - SCOPUS:34250292819

SN - 0568-5230

VL - 25

SP - 1332

EP - 1334

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 6

ER -

Internal rotation barriers in esters of N,N-dimethyldithiocarbamic acid

Abstract

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