Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane

I. D. Kalikhman; N. S. Vyazankin; V. A. Pestunovich; L. I. Belousova; P. V. Makerov

doi:10.1007/BF01108232

Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane

I. D. Kalikhman, N. S. Vyazankin, V. A. Pestunovich, L. I. Belousova, P. V. Makerov

Research output: Contribution to journal › Article › peer-review

Abstract

1. It was established via NMR that triethyl(acetylacetonato)germane is a mixture of the cis- and trans-isomers of triethylgennoxy-2-penten-4-one. The cis-isomer undergoes intramolecular 1,5-rearrangement. 2. cis-trans Transitions were detected in the undiluted triethylgermoxy-2-penten-4-one, which are caused by intermolecular rearrangements via coordination of the germanium atom with the carbonyl group of the adjacent molecule.

Original language	English
Pages (from-to)	887-889
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	4
DOIs	https://doi.org/10.1007/BF01108232
State	Published - 1 Jan 1977
Externally published	Yes

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General Chemistry

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title = "Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane",

abstract = "1. It was established via NMR that triethyl(acetylacetonato)germane is a mixture of the cis- and trans-isomers of triethylgennoxy-2-penten-4-one. The cis-isomer undergoes intramolecular 1,5-rearrangement. 2. cis-trans Transitions were detected in the undiluted triethylgermoxy-2-penten-4-one, which are caused by intermolecular rearrangements via coordination of the germanium atom with the carbonyl group of the adjacent molecule.",

author = "Kalikhman, {I. D.} and Vyazankin, {N. S.} and Pestunovich, {V. A.} and Belousova, {L. I.} and Makerov, {P. V.}",

year = "1977",

month = jan,

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doi = "10.1007/BF01108232",

language = "English",

volume = "26",

pages = "887--889",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane

AU - Kalikhman, I. D.

AU - Vyazankin, N. S.

AU - Pestunovich, V. A.

AU - Belousova, L. I.

AU - Makerov, P. V.

PY - 1977/1/1

Y1 - 1977/1/1

N2 - 1. It was established via NMR that triethyl(acetylacetonato)germane is a mixture of the cis- and trans-isomers of triethylgennoxy-2-penten-4-one. The cis-isomer undergoes intramolecular 1,5-rearrangement. 2. cis-trans Transitions were detected in the undiluted triethylgermoxy-2-penten-4-one, which are caused by intermolecular rearrangements via coordination of the germanium atom with the carbonyl group of the adjacent molecule.

AB - 1. It was established via NMR that triethyl(acetylacetonato)germane is a mixture of the cis- and trans-isomers of triethylgennoxy-2-penten-4-one. The cis-isomer undergoes intramolecular 1,5-rearrangement. 2. cis-trans Transitions were detected in the undiluted triethylgermoxy-2-penten-4-one, which are caused by intermolecular rearrangements via coordination of the germanium atom with the carbonyl group of the adjacent molecule.

UR - http://www.scopus.com/inward/record.url?scp=34250300609&partnerID=8YFLogxK

U2 - 10.1007/BF01108232

DO - 10.1007/BF01108232

M3 - Article

AN - SCOPUS:34250300609

SN - 0568-5230

VL - 26

SP - 887

EP - 889

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 4

ER -

Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane

Abstract

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