Investigation of Bridgehead Effects on Reduction Potential in Alkyl and Aryl Azadithiolate-Bridged (µ-SCH₂XCH₂S) [Fe(CO)₃]₂ Synthetic Analogues of [FeFe]-H₂ase Active Site

Keyphrases

• Active Sites 100%
• Alkyl 100%
• Synthetic Analogues 100%
• Aryl 100%
• Reduction Potential 100%
• Bridged Complexes 100%
• Azadithiolate 100%
• Bridgehead Effect 100%
• Alkylamine 50%
• Arylamines 50%
• Aryl Rings 25%
• Propane 25%
• Stretching Vibration 25%
• Computational Chemistry 25%
• Negative Value 25%
• Density Functional Calculations 25%
• Linear Dependence 25%
• Proton Affinity 25%
• Model Complex 25%
• Geometric Structure 25%
• Lone Pair 25%
• Diiron 25%
• Inductive Effect 25%
• Synthetic Model 25%
• Nitrogen Atom 25%
• Mesomeric Effect 25%
• Hammett Parameter 25%
• Gas Phase Proton Affinity 25%
• Hydrogenase 25%
• Back-bonding 25%

Chemistry

• Reduction Potential 100%
• Proton Affinity 100%
• Density Functional Theory 50%
• Stretching Vibration 50%
• Inductive Effect 50%
• Nitrogen Atom 50%
• Computational Chemistry 50%
• Mesomeric Effect 50%
• Alkylamine 50%
• Hydrogenase 50%