Investigation of the effect of organic solvents on the electrical characteristics of PEDOT:PSS/p-Si heterojunction diodes

C. S. Pathak, R. Kapoor, J. P. Singh, R. Singh

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

Poly (3,4- ethylenedioxythiophene) - poly (styrenesulfonic acid) (PEDOT:PSS) is a widely used polymer in organic electronics. In the present study, spin coated PEDOT:PSS films on Si substrates and doped with different organic solvents were analyzed. The influence of different solvents such as n-methyl-2-pyrrolidone, dimethyl formamide, dimethyl sulfoxide, ethylene glycol, and methanol on the morphology, transmittance and work function of PEDOT:PSS films as well as on the electrical properties of Au/PEDOT:PSS/p-Si/In-Ga heterojunction diodes is presented. It is shown that PEDOT:PSS films doped by various organic solvents exhibited improved conductivity (by two orders of magnitude) and transparency (> 85%) in the visible region. Various organic solvents modified heterojunction diodes studied in this work showed rectifying behavior with ideality factors in the range of 1.9–3.2.

Original languageEnglish
Pages (from-to)115-121
Number of pages7
JournalThin Solid Films
Volume622
DOIs
StatePublished - 31 Jan 2017
Externally publishedYes

Keywords

  • Electrical properties
  • Heterojunction
  • Kelvin probe force microscopy
  • PEDOT:PSS
  • Solvents

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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