Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

I. D. Kalikhman; D. A. Bravo-Zhivotovskii; B. Z. Pertsikov; V. A. Pestunovich; O. A. Kruglaya; N. S. Vyazankin

doi:10.1007/BF00951875

Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

I. D. Kalikhman, D. A. Bravo-Zhivotovskii, B. Z. Pertsikov, V. A. Pestunovich, O. A. Kruglaya, N. S. Vyazankin

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Abstract

1. The processes involved in the solvation of Et₃GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et₃GeLi·nL complexes which form were determined. 2. It was shown that the structure of the ion pair of Et₃GeLi in donating solvents at various temperatures can be determined from the PMR spectra.

Original language	English
Pages (from-to)	43-47
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	29
Issue number	1
DOIs	https://doi.org/10.1007/BF00951875
State	Published - 1 Jan 1980
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00951875

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title = "Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy",

abstract = "1. The processes involved in the solvation of Et3GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et3GeLi·nL complexes which form were determined. 2. It was shown that the structure of the ion pair of Et3GeLi in donating solvents at various temperatures can be determined from the PMR spectra.",

author = "Kalikhman, {I. D.} and Bravo-Zhivotovskii, {D. A.} and Pertsikov, {B. Z.} and Pestunovich, {V. A.} and Kruglaya, {O. A.} and Vyazankin, {N. S.}",

year = "1980",

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doi = "10.1007/BF00951875",

language = "English",

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T1 - Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

AU - Kalikhman, I. D.

AU - Bravo-Zhivotovskii, D. A.

AU - Pertsikov, B. Z.

AU - Pestunovich, V. A.

AU - Kruglaya, O. A.

AU - Vyazankin, N. S.

PY - 1980/1/1

Y1 - 1980/1/1

N2 - 1. The processes involved in the solvation of Et3GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et3GeLi·nL complexes which form were determined. 2. It was shown that the structure of the ion pair of Et3GeLi in donating solvents at various temperatures can be determined from the PMR spectra.

AB - 1. The processes involved in the solvation of Et3GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et3GeLi·nL complexes which form were determined. 2. It was shown that the structure of the ion pair of Et3GeLi in donating solvents at various temperatures can be determined from the PMR spectra.

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U2 - 10.1007/BF00951875

DO - 10.1007/BF00951875

M3 - Article

AN - SCOPUS:34250239987

SN - 0568-5230

VL - 29

SP - 43

EP - 47

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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ER -

Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

Abstract

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