Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry

Yury Kostyukevich; Anna Stavitskaya; Alexander Zherebker; Marina Konstantinova; Mikhail Vlaskin; Ludmila Borisova; Alexey Kononikhin; Igor Popov; Eugene Nikolaev

doi:10.1177/1469066717718836

Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry

Yury Kostyukevich, Anna Stavitskaya, Alexander Zherebker, Marina Konstantinova, Mikhail Vlaskin, Ludmila Borisova, Alexey Kononikhin, Igor Popov, Eugene Nikolaev

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Natural complex mixtures such as oil and dissolved organic matter play an important role in the economy and in the global carbon cycle. One of the most promising approaches for the investigation of the chemical structure of such substances is the combination of the high-resolution mass spectrometry and selective chemical reactions. Here, we report the investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. Ozonation of crude oil results in the appearance of the new compounds with high content (up to 9 atom) of oxygen. Isotopic exchange reaction showed that those oxygen stem from the carbonyl groups. Ozonation of the dissolved organic matter leads to the destruction of the substance and shift towards the region of the saturated compounds.

Original language	English
Pages (from-to)	152-155
Number of pages	4
Journal	European Journal of Mass Spectrometry
Volume	23
Issue number	4
DOIs	https://doi.org/10.1177/1469066717718836
State	Published - 1 Aug 2017
Externally published	Yes

Keywords

Fourier transform ion cyclotron resonance
Oil
crude oil
dissolved organic matter
electrospray ionization
humic acids
ozone

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy

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10.1177/1469066717718836

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Kostyukevich, Y., Stavitskaya, A., Zherebker, A., Konstantinova, M., Vlaskin, M., Borisova, L., Kononikhin, A., Popov, I., & Nikolaev, E. (2017). Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. European Journal of Mass Spectrometry, 23(4), 152-155. https://doi.org/10.1177/1469066717718836

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title = "Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry",

abstract = "Natural complex mixtures such as oil and dissolved organic matter play an important role in the economy and in the global carbon cycle. One of the most promising approaches for the investigation of the chemical structure of such substances is the combination of the high-resolution mass spectrometry and selective chemical reactions. Here, we report the investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. Ozonation of crude oil results in the appearance of the new compounds with high content (up to 9 atom) of oxygen. Isotopic exchange reaction showed that those oxygen stem from the carbonyl groups. Ozonation of the dissolved organic matter leads to the destruction of the substance and shift towards the region of the saturated compounds.",

keywords = "Fourier transform ion cyclotron resonance, Oil, crude oil, dissolved organic matter, electrospray ionization, humic acids, ozone",

author = "Yury Kostyukevich and Anna Stavitskaya and Alexander Zherebker and Marina Konstantinova and Mikhail Vlaskin and Ludmila Borisova and Alexey Kononikhin and Igor Popov and Eugene Nikolaev",

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year = "2017",

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doi = "10.1177/1469066717718836",

language = "English",

volume = "23",

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Kostyukevich, Y, Stavitskaya, A, Zherebker, A, Konstantinova, M, Vlaskin, M, Borisova, L, Kononikhin, A, Popov, I & Nikolaev, E 2017, 'Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry', European Journal of Mass Spectrometry, vol. 23, no. 4, pp. 152-155. https://doi.org/10.1177/1469066717718836

TY - JOUR

T1 - Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry

AU - Kostyukevich, Yury

AU - Stavitskaya, Anna

AU - Zherebker, Alexander

AU - Konstantinova, Marina

AU - Vlaskin, Mikhail

AU - Borisova, Ludmila

AU - Kononikhin, Alexey

AU - Popov, Igor

AU - Nikolaev, Eugene

PY - 2017/8/1

Y1 - 2017/8/1

N2 - Natural complex mixtures such as oil and dissolved organic matter play an important role in the economy and in the global carbon cycle. One of the most promising approaches for the investigation of the chemical structure of such substances is the combination of the high-resolution mass spectrometry and selective chemical reactions. Here, we report the investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. Ozonation of crude oil results in the appearance of the new compounds with high content (up to 9 atom) of oxygen. Isotopic exchange reaction showed that those oxygen stem from the carbonyl groups. Ozonation of the dissolved organic matter leads to the destruction of the substance and shift towards the region of the saturated compounds.

AB - Natural complex mixtures such as oil and dissolved organic matter play an important role in the economy and in the global carbon cycle. One of the most promising approaches for the investigation of the chemical structure of such substances is the combination of the high-resolution mass spectrometry and selective chemical reactions. Here, we report the investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. Ozonation of crude oil results in the appearance of the new compounds with high content (up to 9 atom) of oxygen. Isotopic exchange reaction showed that those oxygen stem from the carbonyl groups. Ozonation of the dissolved organic matter leads to the destruction of the substance and shift towards the region of the saturated compounds.

KW - Fourier transform ion cyclotron resonance

KW - Oil

KW - crude oil

KW - dissolved organic matter

KW - electrospray ionization

KW - humic acids

KW - ozone

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U2 - 10.1177/1469066717718836

DO - 10.1177/1469066717718836

M3 - Article

C2 - 29028389

AN - SCOPUS:85038127024

SN - 1469-0667

VL - 23

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EP - 155

JO - European Journal of Mass Spectrometry

JF - European Journal of Mass Spectrometry

IS - 4

ER -

Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry

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Keywords

ASJC Scopus subject areas

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