Investigation of ZrFe2 and ZrCo2 under very high pressure of gaseous hydrogen and deuterium

S. M. Filipek; I. Jacob; V. Paul-Boncour; A. Percheron-Guegan; I. Marchuk; D. Mogilyanski; J. Pielaszek

Investigation of ZrFe₂ and ZrCo₂ under very high pressure of gaseous hydrogen and deuterium

S. M. Filipek, I. Jacob, V. Paul-Boncour, A. Percheron-Guegan, I. Marchuk, D. Mogilyanski, J. Pielaszek

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

New hydrides and deuterides of Laves cubic phases ZrFe₂ and ZrCo₂ were synthesized by high hydrogen (deuterium) pressure technique. For both Laves phases the symmetry of lattice does not change but a large expansion of lattice parameter (by 8% for ZrFe₂ and by 4.5% for ZrCo₂) occurs during hydrides (deuterides) formation. In contrast to the relatively stable hydride (if stored in an inert atmosphere) formed in ZrFe₂, the ZrCo₂H₂ decomposes easily at 25°C. Large lattice expansion of ZrFe₂ during the deuteride formation changes only slightly its magnetic properties.

Original language	English
Pages (from-to)	1921-1926
Number of pages	6
Journal	Polish Journal of Chemistry
Volume	75
Issue number	12
State	Published - 1 Dec 2001

Keywords

Deuterides
High pressure
Hydrides
Laves phase

ASJC Scopus subject areas

General Chemistry

Cite this

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title = "Investigation of ZrFe2 and ZrCo2 under very high pressure of gaseous hydrogen and deuterium",

abstract = "New hydrides and deuterides of Laves cubic phases ZrFe2 and ZrCo2 were synthesized by high hydrogen (deuterium) pressure technique. For both Laves phases the symmetry of lattice does not change but a large expansion of lattice parameter (by 8% for ZrFe2 and by 4.5% for ZrCo2) occurs during hydrides (deuterides) formation. In contrast to the relatively stable hydride (if stored in an inert atmosphere) formed in ZrFe2, the ZrCo2H2 decomposes easily at 25°C. Large lattice expansion of ZrFe2 during the deuteride formation changes only slightly its magnetic properties.",

keywords = "Deuterides, High pressure, Hydrides, Laves phase",

author = "Filipek, {S. M.} and I. Jacob and V. Paul-Boncour and A. Percheron-Guegan and I. Marchuk and D. Mogilyanski and J. Pielaszek",

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language = "English",

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TY - JOUR

T1 - Investigation of ZrFe2 and ZrCo2 under very high pressure of gaseous hydrogen and deuterium

AU - Filipek, S. M.

AU - Jacob, I.

AU - Paul-Boncour, V.

AU - Percheron-Guegan, A.

AU - Marchuk, I.

AU - Mogilyanski, D.

AU - Pielaszek, J.

PY - 2001/12/1

Y1 - 2001/12/1

N2 - New hydrides and deuterides of Laves cubic phases ZrFe2 and ZrCo2 were synthesized by high hydrogen (deuterium) pressure technique. For both Laves phases the symmetry of lattice does not change but a large expansion of lattice parameter (by 8% for ZrFe2 and by 4.5% for ZrCo2) occurs during hydrides (deuterides) formation. In contrast to the relatively stable hydride (if stored in an inert atmosphere) formed in ZrFe2, the ZrCo2H2 decomposes easily at 25°C. Large lattice expansion of ZrFe2 during the deuteride formation changes only slightly its magnetic properties.

AB - New hydrides and deuterides of Laves cubic phases ZrFe2 and ZrCo2 were synthesized by high hydrogen (deuterium) pressure technique. For both Laves phases the symmetry of lattice does not change but a large expansion of lattice parameter (by 8% for ZrFe2 and by 4.5% for ZrCo2) occurs during hydrides (deuterides) formation. In contrast to the relatively stable hydride (if stored in an inert atmosphere) formed in ZrFe2, the ZrCo2H2 decomposes easily at 25°C. Large lattice expansion of ZrFe2 during the deuteride formation changes only slightly its magnetic properties.

KW - Deuterides

KW - High pressure

KW - Hydrides

KW - Laves phase

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M3 - Article

AN - SCOPUS:0035648074

SN - 0137-5083

VL - 75

SP - 1921

EP - 1926

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 12

ER -

Investigation of ZrFe₂ and ZrCo₂ under very high pressure of gaseous hydrogen and deuterium

Abstract

Keywords

ASJC Scopus subject areas

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