Ionic species derived from tetrathiafulvalenes (TTFs): cation-radicals vs cations

M. Giffard; M. Sigalov; V. Khodorkovsky; A. Gorgues; G. Mabon

doi:10.1016/S0379-6779(98)00877-7

Ionic species derived from tetrathiafulvalenes (TTFs): cation-radicals vs cations

M. Giffard, M. Sigalov, V. Khodorkovsky, A. Gorgues, G. Mabon

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

5 Scopus citations

Abstract

Action of acids on TTFs affords cation radicals or/and protonated species, depending on conditions and substituents. The reaction of TTF derivatives with acids has been monitored using UV-Vis and nmr spectroscopy. Stoichiometric cation-radical salts have been synthesized by preparative oxidation of TTFs using phenyliodoso diacetate and an acid for comparison. A general scheme for the interaction of TTFs with acids is suggested.

Original language	English
Pages (from-to)	1713
Number of pages	1
Journal	Synthetic Metals
Volume	102
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00877-7
State	Published - 1 Jan 1999
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 12 Jul 1998 → 18 Jul 1998

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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abstract = "Action of acids on TTFs affords cation radicals or/and protonated species, depending on conditions and substituents. The reaction of TTF derivatives with acids has been monitored using UV-Vis and nmr spectroscopy. Stoichiometric cation-radical salts have been synthesized by preparative oxidation of TTFs using phenyliodoso diacetate and an acid for comparison. A general scheme for the interaction of TTFs with acids is suggested.",

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T1 - Ionic species derived from tetrathiafulvalenes (TTFs)

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

AU - Giffard, M.

AU - Sigalov, M.

AU - Khodorkovsky, V.

AU - Gorgues, A.

AU - Mabon, G.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Action of acids on TTFs affords cation radicals or/and protonated species, depending on conditions and substituents. The reaction of TTF derivatives with acids has been monitored using UV-Vis and nmr spectroscopy. Stoichiometric cation-radical salts have been synthesized by preparative oxidation of TTFs using phenyliodoso diacetate and an acid for comparison. A general scheme for the interaction of TTFs with acids is suggested.

AB - Action of acids on TTFs affords cation radicals or/and protonated species, depending on conditions and substituents. The reaction of TTF derivatives with acids has been monitored using UV-Vis and nmr spectroscopy. Stoichiometric cation-radical salts have been synthesized by preparative oxidation of TTFs using phenyliodoso diacetate and an acid for comparison. A general scheme for the interaction of TTFs with acids is suggested.

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U2 - 10.1016/S0379-6779(98)00877-7

DO - 10.1016/S0379-6779(98)00877-7

M3 - Conference article

AN - SCOPUS:58449097102

SN - 0379-6779

VL - 102

SP - 1713

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

Y2 - 12 July 1998 through 18 July 1998

ER -

Ionic species derived from tetrathiafulvalenes (TTFs): cation-radicals vs cations

Abstract

ASJC Scopus subject areas

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