Ions do not catalyze the decomposition of peroxomonosulfate

Ludmila Pochtarenko; Israel Zilbermann; Dror Shamir; Dan Meyerstein

doi:10.1080/00958972.2013.863880

Ions do not catalyze the decomposition of peroxomonosulfate

Ludmila Pochtarenko, Israel Zilbermann, Dror Shamir, Dan Meyerstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

According to literature reports, the spontaneous decomposition of peroxomonosulfate is catalyzed by transition metal ions, e.g. by Co(II), Fe(II), Fe(III), and Ni(II). The present study demonstrates that this is not the case for at pH ~ 1.9. This observation is of importance as peroxomonosulfate is used as an oxidant in a variety of important processes. The reasons for this exception are discussed.

Original language	English
Pages (from-to)	4355-4362
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	66
Issue number	24
DOIs	https://doi.org/10.1080/00958972.2013.863880
State	Published - 20 Dec 2013

Keywords

Fe(III) ion

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958972.2013.863880

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abstract = "According to literature reports, the spontaneous decomposition of peroxomonosulfate is catalyzed by transition metal ions, e.g. by Co(II), Fe(II), Fe(III), and Ni(II). The present study demonstrates that this is not the case for at pH ~ 1.9. This observation is of importance as peroxomonosulfate is used as an oxidant in a variety of important processes. The reasons for this exception are discussed.",

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AU - Shamir, Dror

AU - Meyerstein, Dan

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N2 - According to literature reports, the spontaneous decomposition of peroxomonosulfate is catalyzed by transition metal ions, e.g. by Co(II), Fe(II), Fe(III), and Ni(II). The present study demonstrates that this is not the case for at pH ~ 1.9. This observation is of importance as peroxomonosulfate is used as an oxidant in a variety of important processes. The reasons for this exception are discussed.

AB - According to literature reports, the spontaneous decomposition of peroxomonosulfate is catalyzed by transition metal ions, e.g. by Co(II), Fe(II), Fe(III), and Ni(II). The present study demonstrates that this is not the case for at pH ~ 1.9. This observation is of importance as peroxomonosulfate is used as an oxidant in a variety of important processes. The reasons for this exception are discussed.

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ER -

Ions do not catalyze the decomposition of peroxomonosulfate

Abstract

Keywords

ASJC Scopus subject areas

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