Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes

A. A. Pasynskii, S. S. Shapovalov, O. A. Tikhonova, I. V. Skabitskii, Y. U.V. Torubaev, S. G. Sakharov

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12 Scopus citations

Abstract

The reactions of CpFe(CO)(PPh3)TePh (I) with CpMn(CO)2(THF), W(CO)5(THF), and [Cp RhCl2]2 gave heterometallic adducts CpFe(CO)(PPh3)(μ-TePh)CpMn(CO)2 (II), CpFe(CO)(PPh3)(μ-TePh)W(CO)5 (III), and CpFe(CO)(PPh3)(μ-TePh)RhCl2Cp(IV). The structures of II, III, and IV · 3CDCl3 (CIF files CCDC nos. 063654, 1063655, 1038123) were studied by X-ray diffraction. In all complexes, metal atoms are connected by only one tellurophenyl bridge. All M → Te bonds are substantially shortened with respect to the sum of the covalent radii owing to the additional M → Te dative interactions.

Original languageEnglish
Pages (from-to)741-746
Number of pages6
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume41
Issue number11
DOIs
StatePublished - 1 Nov 2015
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering

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