Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes

A. A. Pasynskii; S. S. Shapovalov; O. A. Tikhonova; I. V. Skabitskii; Y. U.V. Torubaev; S. G. Sakharov

doi:10.1134/S1070328415110068

Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes

A. A. Pasynskii
, S. S. Shapovalov
, O. A. Tikhonova
, I. V. Skabitskii
, Y. U.V. Torubaev
, S. G. Sakharov

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reactions of CpFe(CO)(PPh₃)TePh (I) with CpMn(CO)₂(THF), W(CO)₅(THF), and [Cp RhCl₂]₂ gave heterometallic adducts CpFe(CO)(PPh₃)(μ-TePh)CpMn(CO)₂ (II), CpFe(CO)(PPh₃)(μ-TePh)W(CO)₅ (III), and CpFe(CO)(PPh₃)(μ-TePh)RhCl₂Cp(IV). The structures of II, III, and IV · 3CDCl₃ (CIF files CCDC nos. 063654, 1063655, 1038123) were studied by X-ray diffraction. In all complexes, metal atoms are connected by only one tellurophenyl bridge. All M → Te bonds are substantially shortened with respect to the sum of the covalent radii owing to the additional M → Te dative interactions.

Original language	English
Pages (from-to)	741-746
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	41
Issue number	11
DOIs	https://doi.org/10.1134/S1070328415110068
State	Published - 1 Nov 2015
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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Pasynskii, A. A., Shapovalov, S. S., Tikhonova, O. A., Skabitskii, I. V., Torubaev, Y. U. V., & Sakharov, S. G. (2015). Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 41(11), 741-746. https://doi.org/10.1134/S1070328415110068

@article{0c174951154a4a8b8a47b80cf9434bd8,

title = "Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes",

abstract = "The reactions of CpFe(CO)(PPh3)TePh (I) with CpMn(CO)2(THF), W(CO)5(THF), and [Cp RhCl2]2 gave heterometallic adducts CpFe(CO)(PPh3)(μ-TePh)CpMn(CO)2 (II), CpFe(CO)(PPh3)(μ-TePh)W(CO)5 (III), and CpFe(CO)(PPh3)(μ-TePh)RhCl2Cp(IV). The structures of II, III, and IV · 3CDCl3 (CIF files CCDC nos. 063654, 1063655, 1038123) were studied by X-ray diffraction. In all complexes, metal atoms are connected by only one tellurophenyl bridge. All M → Te bonds are substantially shortened with respect to the sum of the covalent radii owing to the additional M → Te dative interactions.",

author = "Pasynskii, \{A. A.\} and Shapovalov, \{S. S.\} and Tikhonova, \{O. A.\} and Skabitskii, \{I. V.\} and Torubaev, \{Y. U.V.\} and Sakharov, \{S. G.\}",

note = "Publisher Copyright: {\textcopyright} 2015 Pleiades Publishing, Ltd.",

year = "2015",

month = nov,

day = "1",

doi = "10.1134/S1070328415110068",

language = "English",

volume = "41",

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journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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TY - JOUR

T1 - Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes

AU - Pasynskii, A. A.

AU - Shapovalov, S. S.

AU - Tikhonova, O. A.

AU - Skabitskii, I. V.

AU - Torubaev, Y. U.V.

AU - Sakharov, S. G.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - The reactions of CpFe(CO)(PPh3)TePh (I) with CpMn(CO)2(THF), W(CO)5(THF), and [Cp RhCl2]2 gave heterometallic adducts CpFe(CO)(PPh3)(μ-TePh)CpMn(CO)2 (II), CpFe(CO)(PPh3)(μ-TePh)W(CO)5 (III), and CpFe(CO)(PPh3)(μ-TePh)RhCl2Cp(IV). The structures of II, III, and IV · 3CDCl3 (CIF files CCDC nos. 063654, 1063655, 1038123) were studied by X-ray diffraction. In all complexes, metal atoms are connected by only one tellurophenyl bridge. All M → Te bonds are substantially shortened with respect to the sum of the covalent radii owing to the additional M → Te dative interactions.

AB - The reactions of CpFe(CO)(PPh3)TePh (I) with CpMn(CO)2(THF), W(CO)5(THF), and [Cp RhCl2]2 gave heterometallic adducts CpFe(CO)(PPh3)(μ-TePh)CpMn(CO)2 (II), CpFe(CO)(PPh3)(μ-TePh)W(CO)5 (III), and CpFe(CO)(PPh3)(μ-TePh)RhCl2Cp(IV). The structures of II, III, and IV · 3CDCl3 (CIF files CCDC nos. 063654, 1063655, 1038123) were studied by X-ray diffraction. In all complexes, metal atoms are connected by only one tellurophenyl bridge. All M → Te bonds are substantially shortened with respect to the sum of the covalent radii owing to the additional M → Te dative interactions.

UR - https://www.scopus.com/pages/publications/84946095628

U2 - 10.1134/S1070328415110068

DO - 10.1134/S1070328415110068

M3 - Article

AN - SCOPUS:84946095628

SN - 1070-3284

VL - 41

SP - 741

EP - 746

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 11

ER -

Iron cyclopentadienyl(triphenylphosphine)carbonylphenyl telluride adducts with manganese, tungsten, and rhodium complexes

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