Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol

M. V. Landau; G. Satishkumar; T. Buzaglo; M. Herskowitz

Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol

M. V. Landau, G. Satishkumar, T. Buzaglo, M. Herskowitz

Department of Chemical Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

Catalytic wet peroxide oxidation is a promising method to treat industrial wastewaters containing phenols. The main problem associated with heterogeneous Fenton catalysts comes from the leaching of the active phase when oxidation is carried out at pH near 3, the optimum value for the homogeneous Fenton process. This problem was overcome by modifying the state of iron using isolated iron ions embedded in mesoporous silica and carbon CMK-3. Isolated Fe(3+) ions displayed the highest activity due to their lowest coordinative saturation. This allowed increasing the working pH to 4-5 solving the problem of iron leaching. This is an abstract of a paper presented at the 7th European Congress of Chemical Engineering-7 and 19th International Congress of Chemical and Process Engineering CHISA (Prague, Czech Republic 8/28/2010-9/1/2010).

Original language	English
State	Published - 1 Dec 2010
Event	19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7 - Prague, Czech Republic Duration: 28 Aug 2010 → 1 Sep 2010

Conference

Conference	19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7
Country/Territory	Czech Republic
City	Prague
Period	28/08/10 → 1/09/10

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Process Chemistry and Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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Landau, M. V., Satishkumar, G., Buzaglo, T., & Herskowitz, M. (2010). Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol. Paper presented at 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, Prague, Czech Republic.

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title = "Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol",

abstract = "Catalytic wet peroxide oxidation is a promising method to treat industrial wastewaters containing phenols. The main problem associated with heterogeneous Fenton catalysts comes from the leaching of the active phase when oxidation is carried out at pH near 3, the optimum value for the homogeneous Fenton process. This problem was overcome by modifying the state of iron using isolated iron ions embedded in mesoporous silica and carbon CMK-3. Isolated Fe(3+) ions displayed the highest activity due to their lowest coordinative saturation. This allowed increasing the working pH to 4-5 solving the problem of iron leaching. This is an abstract of a paper presented at the 7th European Congress of Chemical Engineering-7 and 19th International Congress of Chemical and Process Engineering CHISA (Prague, Czech Republic 8/28/2010-9/1/2010).",

author = "Landau, {M. V.} and G. Satishkumar and T. Buzaglo and M. Herskowitz",

year = "2010",

month = dec,

day = "1",

language = "English",

note = "19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7 ; Conference date: 28-08-2010 Through 01-09-2010",

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Landau, MV, Satishkumar, G, Buzaglo, T & Herskowitz, M 2010, 'Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol', Paper presented at 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, Prague, Czech Republic, 28/08/10 - 1/09/10.

Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol. / Landau, M. V.; Satishkumar, G.; Buzaglo, T. et al.
2010. Paper presented at 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, Prague, Czech Republic.

Research output: Contribution to conference › Paper › peer-review

TY - CONF

T1 - Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol

AU - Landau, M. V.

AU - Satishkumar, G.

AU - Buzaglo, T.

AU - Herskowitz, M.

PY - 2010/12/1

Y1 - 2010/12/1

N2 - Catalytic wet peroxide oxidation is a promising method to treat industrial wastewaters containing phenols. The main problem associated with heterogeneous Fenton catalysts comes from the leaching of the active phase when oxidation is carried out at pH near 3, the optimum value for the homogeneous Fenton process. This problem was overcome by modifying the state of iron using isolated iron ions embedded in mesoporous silica and carbon CMK-3. Isolated Fe(3+) ions displayed the highest activity due to their lowest coordinative saturation. This allowed increasing the working pH to 4-5 solving the problem of iron leaching. This is an abstract of a paper presented at the 7th European Congress of Chemical Engineering-7 and 19th International Congress of Chemical and Process Engineering CHISA (Prague, Czech Republic 8/28/2010-9/1/2010).

AB - Catalytic wet peroxide oxidation is a promising method to treat industrial wastewaters containing phenols. The main problem associated with heterogeneous Fenton catalysts comes from the leaching of the active phase when oxidation is carried out at pH near 3, the optimum value for the homogeneous Fenton process. This problem was overcome by modifying the state of iron using isolated iron ions embedded in mesoporous silica and carbon CMK-3. Isolated Fe(3+) ions displayed the highest activity due to their lowest coordinative saturation. This allowed increasing the working pH to 4-5 solving the problem of iron leaching. This is an abstract of a paper presented at the 7th European Congress of Chemical Engineering-7 and 19th International Congress of Chemical and Process Engineering CHISA (Prague, Czech Republic 8/28/2010-9/1/2010).

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M3 - Paper

AN - SCOPUS:84864303290

T2 - 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7

Y2 - 28 August 2010 through 1 September 2010

ER -

Landau MV, Satishkumar G, Buzaglo T, Herskowitz M. Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol. 2010. Paper presented at 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, Prague, Czech Republic.

Iron ions encapsulated in mesostructured matrices as efficient and leach less catalysts for catalytic wet peroxide oxidation of phenol

Abstract

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UN SDGs

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