Iron Phosphate Catalyzed Asymmetric Cross-Dehydrogenative Coupling of 2-Naphthols with β-Ketoesters

Sachin Narute, Doron Pappo

Research output: Contribution to journalArticlepeer-review

46 Scopus citations

Abstract

Chiral iron phosphate complexes were successfully exploited for asymmetric cross-dehydrogenative coupling reactions between 2-naphthols and β-ketoester derivatives. On the basis of kinetic studies, it is suggested that iron monophosphate complexes constitute the active catalysts that induce stereoselectivity during the carbon-carbon bond-formation step.

Original languageEnglish
Pages (from-to)2917-2920
Number of pages4
JournalOrganic Letters
Volume19
Issue number11
DOIs
StatePublished - 2 Jun 2017

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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