Abstract
The unimolecular dissociation reaction of the propylene oxide cation-radical to the acetyl cation plus the methyl radical was studied by means of carbon-13 labeling and MS/MS techniques. In one of the dissociation pathways, in which acetone ion is presumably an intermediate, the newly formed methyl is lost preferentially to the pre-existing methyl. Propylene oxide demonstrates non-ergodic behavior.
Original language | English |
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Pages (from-to) | 253-262 |
Number of pages | 10 |
Journal | International Journal of Mass Spectrometry and Ion Processes |
Volume | 72 |
Issue number | 3 |
DOIs | |
State | Published - 29 Oct 1986 |
Externally published | Yes |
ASJC Scopus subject areas
- Spectroscopy