Isobaric Vapor-Liquid Equilibria In The Binary Systems Of 1, 3-Dioxolane, 1-Chlorobutane And 2-Chlorobut Ane

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Abstract

Vapor-liquid equilibrium at 101.3 kPa has been determined for the binary systems of 1, 3-dioxolane, 1-chlorobutane and 2-chlorobutane. The binary systems 1, 3-dioxolane-chlorobutanes exhibit positive deviations from ideal behavior while the binary 1-chlorobutane-2-chlorobutane behaves ideally. The activity coefficients and boiling point of the solution were correlated with its composition by the Redlich-Kister and Wisniak-Tamir equations.

Original languageEnglish
Pages (from-to)177-185
Number of pages9
JournalPhysics and Chemistry of Liquids
Volume28
Issue number3
DOIs
StatePublished - 1 Nov 1994

Keywords

  • Vapor-liquid equilibrium
  • activities
  • organic solutions

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