Vapor-liquid equilibrium at 101.3 kPa has been determined for the binary systems of 1, 3-dioxolane, 1-chlorobutane and 2-chlorobutane. The binary systems 1, 3-dioxolane-chlorobutanes exhibit positive deviations from ideal behavior while the binary 1-chlorobutane-2-chlorobutane behaves ideally. The activity coefficients and boiling point of the solution were correlated with its composition by the Redlich-Kister and Wisniak-Tamir equations.
- Vapor-liquid equilibrium
- organic solutions