Abstract
Vapor-liquid equilibria at 101.3 kPa have been determined for the binary systems methyl acetate + 1-hexene and 1-hexene + 2-propanol. The binary system methyl acetate + 1-hexene exhibits positive deviations from ideal behavior and an azeotrope that boils at 325.38 K contains 39-1 mol % 1-hexene. The binary system 1-hexene + 2-propanol presents strong deviations from ideality and an azeotrope that boils at 331.67 K and contains 79.60 mol % 1-hexene. The activity coefficients and boiling point of the solution were correlated with its composition by the Redlich-Kister, Wohl, Wilson, UNIQUAC, NRTL, and Wisniak-Tamir equations.
| Original language | English |
|---|---|
| Pages (from-to) | 143-146 |
| Number of pages | 4 |
| Journal | Journal of Chemical and Engineering Data |
| Volume | 41 |
| Issue number | 1 |
| DOIs | |
| State | Published - 1 Jan 1996 |
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering