Kinetics of ligand exchange in uranyl complexes in non-aqueous solvents

Yair Egozy, Shmuel Weiss

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Stopped flow and T-jump experiments were carried out to study the kinetics of the reactions leading to the formation of complexes of the forms UPL and UPL2 where U stands for uranyl, P for TBP and L for 8-hydroxyquinoline or diphenylcarbazone. The experimental results, for CCl4 and CH2ClCH2Cl solutions, provided considerable information on the mechanisms of these reactions as well as numerical values for some of the rate constants and activation energies and entropies.

Original languageEnglish
Pages (from-to)1717-1720
Number of pages4
JournalJournal of Inorganic and Nuclear Chemistry
Volume38
Issue number9
DOIs
StatePublished - 1 Jan 1976
Externally publishedYes

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