Kinetics of radiation‐induced abstraction of hydrogen atoms by CCl3 radicals in the liquid phase: 2,3‐dimethylbutane

Zeev B. Alfassi; Liviu Feldman

doi:10.1002/kin.550120603

Kinetics of radiation‐induced abstraction of hydrogen atoms by CCl₃ radicals in the liquid phase: 2,3‐dimethylbutane

Zeev B. Alfassi, Liviu Feldman

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: (Formula Presented.) and the following rate constants expression was obtained: (Formula Presented.) . The activation energy and the A factor obtained are in good agreement with the values obtained at the gaseous phase, considering the activation energy for self‐diffusion of CCl₄.

Original language	English
Pages (from-to)	379-386
Number of pages	8
Journal	International Journal of Chemical Kinetics
Volume	12
Issue number	6
DOIs	https://doi.org/10.1002/kin.550120603
State	Published - 1 Jan 1980

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1002/kin.550120603

Cite this

@article{cf56142e45ff4246bf2bb994a86c0b56,

title = "Kinetics of radiation‐induced abstraction of hydrogen atoms by CCl3 radicals in the liquid phase: 2,3‐dimethylbutane",

abstract = "The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: (Formula Presented.) and the following rate constants expression was obtained: (Formula Presented.) . The activation energy and the A factor obtained are in good agreement with the values obtained at the gaseous phase, considering the activation energy for self‐diffusion of CCl4.",

author = "Alfassi, {Zeev B.} and Liviu Feldman",

year = "1980",

month = jan,

day = "1",

doi = "10.1002/kin.550120603",

language = "English",

volume = "12",

pages = "379--386",

journal = "International Journal of Chemical Kinetics",

issn = "0538-8066",

publisher = "John Wiley & Sons Inc.",

number = "6",

}

TY - JOUR

T1 - Kinetics of radiation‐induced abstraction of hydrogen atoms by CCl3 radicals in the liquid phase

T2 - 2,3‐dimethylbutane

AU - Alfassi, Zeev B.

AU - Feldman, Liviu

PY - 1980/1/1

Y1 - 1980/1/1

N2 - The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: (Formula Presented.) and the following rate constants expression was obtained: (Formula Presented.) . The activation energy and the A factor obtained are in good agreement with the values obtained at the gaseous phase, considering the activation energy for self‐diffusion of CCl4.

AB - The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: (Formula Presented.) and the following rate constants expression was obtained: (Formula Presented.) . The activation energy and the A factor obtained are in good agreement with the values obtained at the gaseous phase, considering the activation energy for self‐diffusion of CCl4.

UR - http://www.scopus.com/inward/record.url?scp=84985316772&partnerID=8YFLogxK

U2 - 10.1002/kin.550120603

DO - 10.1002/kin.550120603

M3 - Article

AN - SCOPUS:84985316772

SN - 0538-8066

VL - 12

SP - 379

EP - 386

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 6

ER -

Kinetics of radiation‐induced abstraction of hydrogen atoms by CCl₃ radicals in the liquid phase: 2,3‐dimethylbutane

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this