Kinetics of the gas‐phase reaction of allyl alcohol with iodine. The heat of formation and stabilization energy of the hydroxyallyl radical

Ze'ev B. Alfassi; David M. Golden

doi:10.1002/kin.550050211

Kinetics of the gas‐phase reaction of allyl alcohol with iodine. The heat of formation and stabilization energy of the hydroxyallyl radical

Ze'ev B. Alfassi, David M. Golden

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be (Formula Presented.) and k₃ is consistent with the equation (Formula Presented.) From the activation energy and the assumption E_‐3 = 1 ± 1 kcal mol⁻¹, it has been calculated that (Formula Presented.) kcal mol⁻¹. The stabilization energy of the hydroxyallyl radical has been found to be 11.4 ± 2.2 kcal mol⁻¹.

Original language	English
Pages (from-to)	295-303
Number of pages	9
Journal	International Journal of Chemical Kinetics
Volume	5
Issue number	2
DOIs	https://doi.org/10.1002/kin.550050211
State	Published - 1 Jan 1973

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Kinetics of the gas‐phase reaction of allyl alcohol with iodine. The heat of formation and stabilization energy of the hydroxyallyl radical",

abstract = "The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be (Formula Presented.) and k3 is consistent with the equation (Formula Presented.) From the activation energy and the assumption E‐3 = 1 ± 1 kcal mol−1, it has been calculated that (Formula Presented.) kcal mol−1. The stabilization energy of the hydroxyallyl radical has been found to be 11.4 ± 2.2 kcal mol−1.",

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AU - Alfassi, Ze'ev B.

AU - Golden, David M.

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Y1 - 1973/1/1

N2 - The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be (Formula Presented.) and k3 is consistent with the equation (Formula Presented.) From the activation energy and the assumption E‐3 = 1 ± 1 kcal mol−1, it has been calculated that (Formula Presented.) kcal mol−1. The stabilization energy of the hydroxyallyl radical has been found to be 11.4 ± 2.2 kcal mol−1.

AB - The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be (Formula Presented.) and k3 is consistent with the equation (Formula Presented.) From the activation energy and the assumption E‐3 = 1 ± 1 kcal mol−1, it has been calculated that (Formula Presented.) kcal mol−1. The stabilization energy of the hydroxyallyl radical has been found to be 11.4 ± 2.2 kcal mol−1.

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ER -

Kinetics of the gas‐phase reaction of allyl alcohol with iodine. The heat of formation and stabilization energy of the hydroxyallyl radical

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