L-Aspartate links for stable sodium metal-organic frameworks

Peter Siman; Christopher A. Trickett; Hiroyasu Furukawa; Omar M. Yaghi

doi:10.1039/c5cc07578e

L-Aspartate links for stable sodium metal-organic frameworks

Peter Siman, Christopher A. Trickett, Hiroyasu Furukawa, Omar M. Yaghi

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

Original language	English
Pages (from-to)	17463-17466
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	98
DOIs	https://doi.org/10.1039/c5cc07578e
State	Published - 1 Jan 2015
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc07578e

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title = "L-Aspartate links for stable sodium metal-organic frameworks",

abstract = "Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.",

author = "Peter Siman and Trickett, {Christopher A.} and Hiroyasu Furukawa and Yaghi, {Omar M.}",

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AU - Siman, Peter

AU - Trickett, Christopher A.

AU - Furukawa, Hiroyasu

AU - Yaghi, Omar M.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

AB - Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

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SP - 17463

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JO - Chemical Communications

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L-Aspartate links for stable sodium metal-organic frameworks

Abstract

ASJC Scopus subject areas

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