TY - JOUR
T1 - Ligand exchange in uranyl complexes in non-aqueous solutions
T2 - Equilibrium properties
AU - Egozy, Yair
AU - Weiss, Shmuel
PY - 1976/1/1
Y1 - 1976/1/1
N2 - The systems uranyl nitrate, tributylphosphate and 8-hydroxyquinoline or diphenylcarbazone were studied in chloroform, carbon tetrachloride and 1,2-dichloroethane at a number of temperatures. The nature of the complexes formed was determined and the equilibrium constants and several thermodynamic functions were measured. 8-Hydroxyquinoline and diphenylacrbazone will be valuable as indicators for uranyl in kinetic studies. They are also interesting since they participate, along with tributylphosphate, in formation of synergistic complexes.
AB - The systems uranyl nitrate, tributylphosphate and 8-hydroxyquinoline or diphenylcarbazone were studied in chloroform, carbon tetrachloride and 1,2-dichloroethane at a number of temperatures. The nature of the complexes formed was determined and the equilibrium constants and several thermodynamic functions were measured. 8-Hydroxyquinoline and diphenylacrbazone will be valuable as indicators for uranyl in kinetic studies. They are also interesting since they participate, along with tributylphosphate, in formation of synergistic complexes.
UR - http://www.scopus.com/inward/record.url?scp=49349133335&partnerID=8YFLogxK
U2 - 10.1016/0022-1902(76)80666-5
DO - 10.1016/0022-1902(76)80666-5
M3 - Article
AN - SCOPUS:49349133335
SN - 0022-1902
VL - 38
SP - 1713
EP - 1716
JO - Journal of Inorganic and Nuclear Chemistry
JF - Journal of Inorganic and Nuclear Chemistry
IS - 9
ER -