Introduction of a chiral ligand to a series of pentacoordinate silicon complexes led to the assignment of two intramolecular rate processes: Si-N cleavage and pseudorotation. Linear correlations between 15N and 29Si chemical shifts of the complexes, as well as between the latter and the N-methyl exchange barriers were attributed to variation in strength of N→Si coordination.
|Title of host publication||Organosilicon Chemistry Set|
|Subtitle of host publication||From Molecules to Materials|
|Number of pages||6|
|State||Published - 1 Jan 2005|
- Multinuclear NMR
ASJC Scopus subject areas
- Chemistry (all)