Ligation and mediated oxidation of nitrogen monoxide by nickel(II) tetrasulfonated phthalocyanine

Israel Zilbermann, Joseph Hayon, Tsvi Katchalski, Osnat Raveh, Judith Rishpon, Alexander I. Shames, Armand Bettelheim

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16 Scopus citations

Abstract

Ligation and mediated electro-oxidation of NO by the water soluble Ni(II) tetrasulfonated phthalocyanine (Ni(II)TSPc) at pH 7 to 9 is demonstrated using spectroscopic (ultraviolet-visible, Fourier transform infrared, and electron spin resonance) and electrochemical (cyclic voltammetry) techniques. The experimental results are in favor of the formation of a Ni(III)TSPc (NO-) complex in solution.

Original languageEnglish
Pages (from-to)L228-L230
JournalJournal of the Electrochemical Society
Volume144
Issue number8
DOIs
StatePublished - 1 Jan 1997

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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