Light-and Thermal-Activated Olefin Metathesis of Hindered Substrates

Elisa Ivry, Alexander Frenklah, Yakov Ginzburg, Efrat Levin, Israel Goldberg, Sebastian Kozuch, N. Gabriel Lemcoff, Eyal Tzur

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Efficient light-and thermal-Activated metathesis reactions of tetra-substituted olefins were obtained by the S-chelated ruthenium precatalyst Tol-SCF3. Its reactivity in a series of benchmark olefin metathesis reactions was compared to previously reported Mes-SCF3 and a novel sterically congested S-chelated complex, Dipp-SCF3. Tol-SCF3 is thus the first latent catalyst proven to be capable of promoting olefin metathesis of demanding substrates upon light stimulation at room temperature.

Original languageEnglish
Pages (from-to)176-181
Number of pages6
JournalOrganometallics
Volume37
Issue number2
DOIs
StatePublished - 22 Jan 2018

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Light-and Thermal-Activated Olefin Metathesis of Hindered Substrates'. Together they form a unique fingerprint.

Cite this