Light-induced olefin metathesis

Yuval Vidavsky, N. Gabriel Lemcoff

Research output: Contribution to journalReview articlepeer-review

61 Scopus citations

Abstract

Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to modern ruthenium methods based on complex photoisomerisation or indirect photoactivation, this survey of the relevant literature summarises past and present developments in the use of light to expedite olefin ringclosing, ring-opening polymerisation and cross-metathesis reactions.

Original languageEnglish
Pages (from-to)1106-1119
Number of pages14
JournalBeilstein Journal of Organic Chemistry
Volume6
DOIs
StatePublished - 23 Nov 2010

Keywords

  • Catalysis
  • Light activation
  • Olefin metathesis
  • Photoactivation
  • Photoinitiation
  • Photoisomerisation
  • RCM
  • ROMP
  • Ruthenium
  • Tungsten

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