Abstract
Controlled semi-classical approximations for the evolution kernels (the propagators) of the Wigner function in the cases of tunneling and propagation in dispersive media are derived. The semi-classical propagators follow well defined trajectories determined by the local group velocity and a path delay which is a multi-dimensional generalization of Wigner phase-delay time. A comparison between exact and semi-classical time evolution gives good agreement for propagation in dispersive media if the harmonic term in the dispersion relation is the dominant term and excellent agreement for deep tunneling.
| Original language | English |
|---|---|
| Pages (from-to) | 261-267 |
| Number of pages | 7 |
| Journal | Chemical Physics Letters |
| Volume | 396 |
| Issue number | 4-6 |
| DOIs | |
| State | Published - 1 Oct 2004 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry
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