Low-energy resonances in photodissociation of CH+

Sherwin J. Singer, Karl F. Freed, Yehuda B. Band

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Close coupling calculations for the photodissociation cross sections of CH++hv → C+(2P) + H(2S) exhibit near threshold peaks not ascribable only to quasi-bound levels in the A 1Π potential. Our calculations demonstrate the importance of non-adiabatic transitions and thereby suggest the necessity to revise earlier predictions of the rate of radiative association of C+ with H.

Original languageEnglish
Pages (from-to)158-162
Number of pages5
JournalChemical Physics Letters
Volume105
Issue number2
DOIs
StatePublished - 9 Mar 1984

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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