Close coupling calculations for the photodissociation cross sections of CH++hv → C+(2P) + H(2S) exhibit near threshold peaks not ascribable only to quasi-bound levels in the A 1Π potential. Our calculations demonstrate the importance of non-adiabatic transitions and thereby suggest the necessity to revise earlier predictions of the rate of radiative association of C+ with H.
|Number of pages||5|
|Journal||Chemical Physics Letters|
|State||Published - 9 Mar 1984|
ASJC Scopus subject areas
- Physics and Astronomy (all)
- Physical and Theoretical Chemistry