Abstract
The magnetic and magnetocaloric properties of Gd1-xSmxMn2Si2 compounds with 0 ≤ x ≤ 1 have been studied to determine their suitability as magnetic refrigerant materials. The rare earth ordering temperatures are found to decrease from 60 K for x = 0 to 37 K for x = 1. The temperature variations of magnetization under 'field-cooled' and 'zero-field-cooled' conditions are found to differ slightly, indicating a small thermomagnetic irreversibility. Magnetocaloric effect is calculated in terms of isothermal magnetic entropy change (ΔSM) using the magnetization isotherms. The maximum values of ΔSM are found to be 5.9 J kg-1 K-1 in GdMn2Si2 and 3.4 J kg-1 K-1 in SmMn2Si2.
| Original language | English |
|---|---|
| Pages (from-to) | 42-45 |
| Number of pages | 4 |
| Journal | Journal of Alloys and Compounds |
| Volume | 427 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - 16 Jan 2007 |
| Externally published | Yes |
Keywords
- Ferrimagnets
- Magnetic entropy
- Magnetocaloric effect
- Spin fluctuations
ASJC Scopus subject areas
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry
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