Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]-3

J. J. Borrás-Almenar; J. M. Clemente-Juan; E. Coronado; A. V. Palii; B. S. Tsukerblat

doi:10.1063/1.1329892

Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti₂Cl₉]^-3

J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, A. V. Palii, B. S. Tsukerblat

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Abstract

The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.

Original language	English
Pages (from-to)	1148-1164
Number of pages	17
Journal	Journal of Chemical Physics
Volume	114
Issue number	3
DOIs	https://doi.org/10.1063/1.1329892
State	Published - 1 Jan 2001
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.",

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AU - Coronado, E.

AU - Palii, A. V.

AU - Tsukerblat, B. S.

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AB - The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.

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Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti₂Cl₉]^-3

Abstract

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