Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]-3

J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, A. V. Palii, B. S. Tsukerblat

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.

Original languageEnglish
Pages (from-to)1148-1164
Number of pages17
JournalJournal of Chemical Physics
Volume114
Issue number3
DOIs
StatePublished - 1 Jan 2001
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy (all)
  • Physical and Theoretical Chemistry

Fingerprint

Dive into the research topics of 'Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]-3'. Together they form a unique fingerprint.

Cite this