Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]-3

J. J. Borrás-Almenar; J. M. Clemente-Juan; E. Coronado; A. V. Palii; B. S. Tsukerblat

doi:10.1063/1.1329892

Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti₂Cl₉]^-3

J. J. Borrás-Almenar
, J. M. Clemente-Juan
, E. Coronado
, A. V. Palii
, B. S. Tsukerblat

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.

Original language	English
Pages (from-to)	1148-1164
Number of pages	17
Journal	Journal of Chemical Physics
Volume	114
Issue number	3
DOIs	https://doi.org/10.1063/1.1329892
State	Published - 1 Jan 2001
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1329892

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abstract = "The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.",

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AU - Borrás-Almenar, J. J.

AU - Clemente-Juan, J. M.

AU - Coronado, E.

AU - Palii, A. V.

AU - Tsukerblat, B. S.

PY - 2001/1/1

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AB - The theory of the kinetic exchange in a pair of orbitally degenerate ions was applied to the case of face-shared bioctahedral dimer. The effective kinetic exchange was found for the system based on all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals on the energy pattern and magnetic properties of the system was also examined.

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JF - Journal of Chemical Physics

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ER -

Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti₂Cl₉]^-3

Abstract

ASJC Scopus subject areas

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