Magnetic kaolinite immobilized chitosan beads for the removal of Pb(II) and Cd(II) ions from an aqueous environment

S. SD Elanchezhiyan, Perumal Karthikeyan, Karthik Rathinam, M. Hasmath Farzana, Chang Min Park

Research output: Contribution to journalArticlepeer-review

71 Scopus citations

Abstract

In recent decades, magnetic bead material has attracted considerable attention in water and wastewater purification. In this study, the potential of magnetic kaolinite immobilized in chitosan beads (MKa@CB) to remove Pb(II) and Cd(II) ions from an aqueous environment has been successfully investigated. The addition of magnetic kaolinite generates more active sites, whereas that of chitosan enhances the stability of synthesized bead materials, which enable them to effectively interact with the targeted contaminants. Various factors including agitation time, solution pH, and competitive ions were examined to optimize the removal efficiency of the MKa@CB. The adsorption kinetics and isotherm studies indicated that the adsorption fitted well to the pseudo-second-order kinetic model as well as to the Langmuir isotherm. The prepared adsorbent could be reused up to four cycles without any significant adsorption capacity loss. Thus, the synthesized MKa@4%CB can be a promising adsorbent in effectively removing Pb(II) and Cd(II) from water.

Original languageEnglish
Article number117892
JournalCarbohydrate Polymers
Volume261
DOIs
StatePublished - 1 Jun 2021
Externally publishedYes

Keywords

  • Cadmium
  • Chitosan
  • Kaolinite
  • Lead
  • Magnetic beads

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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