Abstract
The temperature behaviour of the spin heat capacity and magnetic moments of dimeric clusters of high-spin iron Fe(II)Fe(III) in charge-ordered crystals is discussed. The employed model, justified in [S.I. Klokishner and B.S. Tsukerblat, Chem. Phys. 125 (1988) 11], includes the intracluster exchange interaction, the "extra" electron transfer (valency detrapping) and the dipole-dipole intercluster interaction. The specific temperature behaviour patterns of the spin heat capacity and magnetic moments are revealed.
Original language | English |
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Pages (from-to) | 141-147 |
Number of pages | 7 |
Journal | Chemical Physics |
Volume | 161 |
Issue number | 1-2 |
DOIs | |
State | Published - 1 Apr 1992 |
Externally published | Yes |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry