Magnetic properties of complex d1 and d5 ions: Crystal field model and Jahn-Teller effect

Kim R. Dunbar, Eric J. Schelter, Boris S. Tsukerblat, Sergei M. Ostrovsky, Vadim Yu Mirovitsky, Andrew V. Palii

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

In this paper, the low lying levels of d1 and low-spin d5 metal complexes possessing ground 2T2 term are considered. Strong spin-orbital interactions is taken into account along with the axial (trigonal or tetragonal) component of the crystal field. In the framework of the semi-classic adiabatic approximation, vibronic Jahn-Teller and pseudo Jahn -Teller interactions acting within the ground manifold are also considered. The influence of the low-symmetry crystal fields, covalence reduction factor, spin-orbital and Jahn-Teller interactions on the anisotropy of g-factors, temperature independent paramagnetic contributions, and magnetic susceptibility is elucidated.

Original languageEnglish
Pages (from-to)2545-2556
Number of pages12
JournalPolyhedron
Volume22
Issue number14-17
DOIs
StatePublished - 15 Jul 2003

Keywords

  • Jahn-Teller effect
  • Magnetic properties
  • d and d metal complexes

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