Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen, Rudi van Eldik, Mohamed Masarwa, Dan Meyerstein

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

Original languageEnglish
Pages (from-to)31-34
Number of pages4
JournalInorganica Chimica Acta
Volume177
Issue number1
DOIs
StatePublished - 1 Nov 1990

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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