Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen; Rudi van Eldik; Mohamed Masarwa; Dan Meyerstein

doi:10.1016/S0020-1693(00)91905-4

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen
, Rudi van Eldik
, Mohamed Masarwa
, Dan Meyerstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The pressure dependence of the reaction Cu(H₂O)_m²⁺ + ^·OH→Cu(III)_aq+OH^-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

Original language	English
Pages (from-to)	31-34
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	177
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)91905-4
State	Published - 1 Nov 1990

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(00)91905-4

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@article{38518695195545cdacbe77049615cfaf,

title = "Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment",

abstract = "The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.",

author = "Haim Cohen and \{van Eldik\}, Rudi and Mohamed Masarwa and Dan Meyerstein",

year = "1990",

month = nov,

day = "1",

doi = "10.1016/S0020-1693(00)91905-4",

language = "English",

volume = "177",

pages = "31--34",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

AU - Cohen, Haim

AU - van Eldik, Rudi

AU - Masarwa, Mohamed

AU - Meyerstein, Dan

PY - 1990/11/1

Y1 - 1990/11/1

N2 - The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

AB - The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

UR - https://www.scopus.com/pages/publications/0001949580

U2 - 10.1016/S0020-1693(00)91905-4

DO - 10.1016/S0020-1693(00)91905-4

M3 - Article

AN - SCOPUS:0001949580

SN - 0020-1693

VL - 177

SP - 31

EP - 34

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Abstract

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