Metal-oxide-based nucleation process under confined conditions: Two mixed-valence V6-type aggregates closing the W48 wheel-type cluster cavities

Achim Müller; Michael T. Pope; Ana Maria Todea; Hartmut Bögge; Joris Van Slageren; Martin Dressel; Pierre Gouzerh; René Thouvenot; Boris Tsukerblat; Aidan Bell

doi:10.1002/anie.200700441

Metal-oxide-based nucleation process under confined conditions: Two mixed-valence V₆-type aggregates closing the W₄₈ wheel-type cluster cavities

Achim Müller, Michael T. Pope, Ana Maria Todea, Hartmut Bögge, Joris Van Slageren, Martin Dressel, Pierre Gouzerh, René Thouvenot, Boris Tsukerblat, Aidan Bell

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Getting together helps: The wheel-shaped {P₈W48} polyoxotungstate (see picture) provides a reaction chamber for the directed assembly of two unprecedented mixed-valence vanadium oxide cavity-capping groups based on linked octahedra and tetrahedra with V^IV and V^V centers, respectively. The magnetic and electronic properties are controlled by the confined conditions.

Original language	English
Pages (from-to)	4477-4480
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	24
DOIs	https://doi.org/10.1002/anie.200700441
State	Published - 26 Jun 2007

Keywords

Confined geometries
Directed-assembly
Electronic structure
Mixed-valent compounds
Polyoxometalates

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200700441

Cite this

Müller, A., Pope, M. T., Todea, A. M., Bögge, H., Van Slageren, J., Dressel, M., Gouzerh, P., Thouvenot, R., Tsukerblat, B., & Bell, A. (2007). Metal-oxide-based nucleation process under confined conditions: Two mixed-valence V₆-type aggregates closing the W₄₈ wheel-type cluster cavities. Angewandte Chemie - International Edition, 46(24), 4477-4480. https://doi.org/10.1002/anie.200700441

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Müller, A, Pope, MT, Todea, AM, Bögge, H, Van Slageren, J, Dressel, M, Gouzerh, P, Thouvenot, R, Tsukerblat, B & Bell, A 2007, 'Metal-oxide-based nucleation process under confined conditions: Two mixed-valence V₆-type aggregates closing the W₄₈ wheel-type cluster cavities', Angewandte Chemie - International Edition, vol. 46, no. 24, pp. 4477-4480. https://doi.org/10.1002/anie.200700441

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AU - Bögge, Hartmut

AU - Van Slageren, Joris

AU - Dressel, Martin

AU - Gouzerh, Pierre

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AU - Tsukerblat, Boris

AU - Bell, Aidan

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