N-Heterocyclic imino-catalyzed 1,4-regioselective azide-alkyne cycloaddition (AAC): a metal-free approach

Shanmugam Revathi; Aditya L. Shinde; Mulimani K. Rajashekhar; Debasish Mandal; Amit Ranjan Maity; Somenath Garai; Tapas Ghatak

doi:10.1039/d3cc04065h

N-Heterocyclic imino-catalyzed 1,4-regioselective azide-alkyne cycloaddition (AAC): a metal-free approach

Shanmugam Revathi, Aditya L. Shinde, Mulimani K. Rajashekhar, Debasish Mandal, Amit Ranjan Maity, Somenath Garai, Tapas Ghatak

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An unprecedented synthetic approach has been devised to efficiently synthesize regioselective 1,4-disubstituted 1,2,3-triazoles. This technique relies on the use of innovative metal-free highly basic N-heterocyclic imino catalysts. The experimental observations have been supported further by TD-DFT computational studies.

Original language	English
Pages (from-to)	12699-12702
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	85
DOIs	https://doi.org/10.1039/d3cc04065h
State	Published - 20 Sep 2023
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc04065h

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abstract = "An unprecedented synthetic approach has been devised to efficiently synthesize regioselective 1,4-disubstituted 1,2,3-triazoles. This technique relies on the use of innovative metal-free highly basic N-heterocyclic imino catalysts. The experimental observations have been supported further by TD-DFT computational studies.",

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T2 - a metal-free approach

AU - Revathi, Shanmugam

AU - Shinde, Aditya L.

AU - Rajashekhar, Mulimani K.

AU - Mandal, Debasish

AU - Maity, Amit Ranjan

AU - Garai, Somenath

AU - Ghatak, Tapas

PY - 2023/9/20

Y1 - 2023/9/20

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AB - An unprecedented synthetic approach has been devised to efficiently synthesize regioselective 1,4-disubstituted 1,2,3-triazoles. This technique relies on the use of innovative metal-free highly basic N-heterocyclic imino catalysts. The experimental observations have been supported further by TD-DFT computational studies.

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U2 - 10.1039/d3cc04065h

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JO - Chemical Communications

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IS - 85

ER -

N-Heterocyclic imino-catalyzed 1,4-regioselective azide-alkyne cycloaddition (AAC): a metal-free approach

Abstract

ASJC Scopus subject areas

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