New approach to filled polymers. Mechanopolymerization on fillers

E. M. Gutman; A. L. Bobovitch

doi:10.1007/BF02719026

New approach to filled polymers. Mechanopolymerization on fillers

E. M. Gutman
, A. L. Bobovitch

Department of Materials Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Mechanopolymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of inorganic fillers Mg(OH)₂ and CaCO₃ was studied. The role of activated surface of fillers was investigated using DSC and FTIR. The influence of milling time and of the filler chemical content on polymerization starting temperature and polymerization enthalpy was studied using DSC. It was shown that an increase of the filler concentration leads to a higher maximum conversion degree. The correlation between conversion kinetics and polymerization enthalpy of the material not polymerized during milling was shown.

Original language	English
Pages (from-to)	245-250
Number of pages	6
Journal	Journal of Thermal Analysis and Calorimetry
Volume	51
Issue number	1
DOIs	https://doi.org/10.1007/BF02719026
State	Published - 1 Jan 1998

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry

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abstract = "Mechanopolymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of inorganic fillers Mg(OH)2 and CaCO3 was studied. The role of activated surface of fillers was investigated using DSC and FTIR. The influence of milling time and of the filler chemical content on polymerization starting temperature and polymerization enthalpy was studied using DSC. It was shown that an increase of the filler concentration leads to a higher maximum conversion degree. The correlation between conversion kinetics and polymerization enthalpy of the material not polymerized during milling was shown.",

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N2 - Mechanopolymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of inorganic fillers Mg(OH)2 and CaCO3 was studied. The role of activated surface of fillers was investigated using DSC and FTIR. The influence of milling time and of the filler chemical content on polymerization starting temperature and polymerization enthalpy was studied using DSC. It was shown that an increase of the filler concentration leads to a higher maximum conversion degree. The correlation between conversion kinetics and polymerization enthalpy of the material not polymerized during milling was shown.

AB - Mechanopolymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of inorganic fillers Mg(OH)2 and CaCO3 was studied. The role of activated surface of fillers was investigated using DSC and FTIR. The influence of milling time and of the filler chemical content on polymerization starting temperature and polymerization enthalpy was studied using DSC. It was shown that an increase of the filler concentration leads to a higher maximum conversion degree. The correlation between conversion kinetics and polymerization enthalpy of the material not polymerized during milling was shown.

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DO - 10.1007/BF02719026

M3 - Article

AN - SCOPUS:0032295299

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JO - Journal of Thermal Analysis and Calorimetry

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New approach to filled polymers. Mechanopolymerization on fillers

Abstract

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