TY - JOUR
T1 - New chemical derivatives based on Vernonia galamensis oil
AU - Grinberg, S.
AU - Kolot, V.
AU - Mills, D.
N1 - Funding Information:
The partial financial support provided by ICA and Hirsh fund is gratefully acknowledged. The authors would also like to thank Dr. David Son-dak from Bromine Compounds Ltd. for kindly performing the TGA analysis.
PY - 1994/1/1
Y1 - 1994/1/1
N2 - Vernonia galamensis, a plant native to Africa, is an excellent source of an epoxy oil of high potential for use in the chemical industry. Vernonia oil was obtained by Soxhlet or room temperature extraction from seeds of accession V-001 of V. galamensis var. ethiopica ssp. galamensis grown in Israel. Room temperature extraction yielded 43-44% of vernonia oil containing a relatively high amount of vernolic acid (72-80%). Vernonia oil was reacted with aliphatic and aromatic diamines to give potential high-value products. In the reaction with aliphatic diamines, amidation gave rise to fatty acid bisamides containing epoxy groups. The reaction of V. galamensis oil with aromatic diamines produced either linear or cross-linked polymers, depending on the reaction conditions.
AB - Vernonia galamensis, a plant native to Africa, is an excellent source of an epoxy oil of high potential for use in the chemical industry. Vernonia oil was obtained by Soxhlet or room temperature extraction from seeds of accession V-001 of V. galamensis var. ethiopica ssp. galamensis grown in Israel. Room temperature extraction yielded 43-44% of vernonia oil containing a relatively high amount of vernolic acid (72-80%). Vernonia oil was reacted with aliphatic and aromatic diamines to give potential high-value products. In the reaction with aliphatic diamines, amidation gave rise to fatty acid bisamides containing epoxy groups. The reaction of V. galamensis oil with aromatic diamines produced either linear or cross-linked polymers, depending on the reaction conditions.
KW - Cross-linked polymers
KW - Diamines
KW - Fatty acid bisamides
KW - Vernonia galamensis
KW - Vernonia oil
UR - http://www.scopus.com/inward/record.url?scp=0010604391&partnerID=8YFLogxK
U2 - 10.1016/0926-6690(94)90084-1
DO - 10.1016/0926-6690(94)90084-1
M3 - Article
AN - SCOPUS:0010604391
SN - 0926-6690
VL - 3
SP - 113
EP - 119
JO - Industrial Crops and Products
JF - Industrial Crops and Products
IS - 1-2
ER -