Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe2(III)Co(II) complex: Evidence of strong orbital contributions

B. S. Tsukerblat; A. V. Palii; V. Yu Mirovitskii; S. M. Ostrovsky; K. Turta; T. Jovmir; S. Shova; J. Bartolome; M. Evangelisti; G. Filoti

doi:10.1063/1.1413988

Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe₂(III)Co(II) complex: Evidence of strong orbital contributions

B. S. Tsukerblat, A. V. Palii, V. Yu Mirovitskii, S. M. Ostrovsky, K. Turta, T. Jovmir, S. Shova, J. Bartolome, M. Evangelisti, G. Filoti

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25 Scopus citations

Abstract

An overview is given on the synthesis and the magnetic behavior of a new μ₃-oxo-bridged heterometallic complex [Fe₂CoO(CH₃COO)₆(3-Cl-Py)₃]. The parameters for Fe-Fe and Fe-Co exchange interactions are revealed and the crucial role of the orbital angular momentum of Co(II) ion and spin-orbit coupling is highlighted.

Original language	English
Pages (from-to)	9528-9535
Number of pages	8
Journal	Journal of Chemical Physics
Volume	115
Issue number	20
DOIs	https://doi.org/10.1063/1.1413988
State	Published - 22 Nov 2001
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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Tsukerblat, B. S., Palii, A. V., Mirovitskii, V. Y., Ostrovsky, S. M., Turta, K., Jovmir, T., Shova, S., Bartolome, J., Evangelisti, M., & Filoti, G. (2001). Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe₂(III)Co(II) complex: Evidence of strong orbital contributions. Journal of Chemical Physics, 115(20), 9528-9535. https://doi.org/10.1063/1.1413988

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abstract = "An overview is given on the synthesis and the magnetic behavior of a new μ3-oxo-bridged heterometallic complex [Fe2CoO(CH3COO)6(3-Cl-Py)3]. The parameters for Fe-Fe and Fe-Co exchange interactions are revealed and the crucial role of the orbital angular momentum of Co(II) ion and spin-orbit coupling is highlighted.",

author = "Tsukerblat, {B. S.} and Palii, {A. V.} and Mirovitskii, {V. Yu} and Ostrovsky, {S. M.} and K. Turta and T. Jovmir and S. Shova and J. Bartolome and M. Evangelisti and G. Filoti",

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doi = "10.1063/1.1413988",

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Tsukerblat, BS, Palii, AV, Mirovitskii, VY, Ostrovsky, SM, Turta, K, Jovmir, T, Shova, S, Bartolome, J, Evangelisti, M & Filoti, G 2001, 'Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe₂(III)Co(II) complex: Evidence of strong orbital contributions', Journal of Chemical Physics, vol. 115, no. 20, pp. 9528-9535. https://doi.org/10.1063/1.1413988

TY - JOUR

T1 - Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe2(III)Co(II) complex

T2 - Evidence of strong orbital contributions

AU - Tsukerblat, B. S.

AU - Palii, A. V.

AU - Mirovitskii, V. Yu

AU - Ostrovsky, S. M.

AU - Turta, K.

AU - Jovmir, T.

AU - Shova, S.

AU - Bartolome, J.

AU - Evangelisti, M.

AU - Filoti, G.

PY - 2001/11/22

Y1 - 2001/11/22

N2 - An overview is given on the synthesis and the magnetic behavior of a new μ3-oxo-bridged heterometallic complex [Fe2CoO(CH3COO)6(3-Cl-Py)3]. The parameters for Fe-Fe and Fe-Co exchange interactions are revealed and the crucial role of the orbital angular momentum of Co(II) ion and spin-orbit coupling is highlighted.

AB - An overview is given on the synthesis and the magnetic behavior of a new μ3-oxo-bridged heterometallic complex [Fe2CoO(CH3COO)6(3-Cl-Py)3]. The parameters for Fe-Fe and Fe-Co exchange interactions are revealed and the crucial role of the orbital angular momentum of Co(II) ion and spin-orbit coupling is highlighted.

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DO - 10.1063/1.1413988

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IS - 20

ER -

Non-Heisenberg magnetic behavior of a triangular bridged heterometallic Fe₂(III)Co(II) complex: Evidence of strong orbital contributions

Abstract

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