Nonplanar conductive surfaces via "bottom-up" nanostructured gold coating

T. P. Vinod, Raz Jelinek

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Development of technologies for the construction of bent, curved, and flexible conductive surfaces is among the most important albeit challenging goals in the promising field of "flexible electronics". We present a generic solution-based "bottom-up" approach for assembling conductive gold nanostructured layers on nonplanar polymer surfaces. The simple two-step experimental scheme is based upon incubation of an amine-displaying polymer [the abundantly used poly(dimethylsiloxane) (PDMS), selected here as a proof of concept] with Au(SCN)4-, followed by a brief treatment with a conductive polymer [poly(3,4-thylenedioxythiophene)/ poly(styrenesulfonate)] solution. Importantly, no reducing agent is co-added to the gold complex solution. The resultant surfaces are conductive and exhibit a unique "nanoribbon" gold morphology. The scheme yields conductive layers upon PDMS in varied configurations: planar, "wrinkled", and mechanically bent surfaces. The technology is simple, inexpensive, and easy to implement for varied polymer surfaces (and other substances), opening the way for practical applications in flexible electronics and related fields.

Original languageEnglish
Pages (from-to)3341-3346
Number of pages6
JournalACS applied materials & interfaces
Volume6
Issue number5
DOIs
StatePublished - 12 Mar 2014

Keywords

  • Au nanostructures
  • bottom-up synthesis
  • conductive gold films
  • flexible electronics
  • poly(dimethylsiloxane) (PDMS)

ASJC Scopus subject areas

  • Materials Science (all)

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