Novel electronic transitions within excited doublets of dimers

Benjamin Scharf; Yehuda B. Band

doi:10.1016/0009-2614(83)87111-5

Novel electronic transitions within excited doublets of dimers

Benjamin Scharf, Yehuda B. Band

Department of Chemistry

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1 Scopus citations

Abstract

We consider the electronic transition between the split components of the excited electronic doublet of a dimer species when the monomer species have permanent dipole moments. We show that the transition moment is given in terms of the permanent dipole moments of the ground and excited states of the monomers. Extension to ionic dimers and transitions between exciton bands in molecular crystals are suggested.

Original language	English
Pages (from-to)	125-128
Number of pages	4
Journal	Chemical Physics Letters
Volume	98
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(83)87111-5
State	Published - 17 Jun 1983

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(83)87111-5

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title = "Novel electronic transitions within excited doublets of dimers",

abstract = "We consider the electronic transition between the split components of the excited electronic doublet of a dimer species when the monomer species have permanent dipole moments. We show that the transition moment is given in terms of the permanent dipole moments of the ground and excited states of the monomers. Extension to ionic dimers and transitions between exciton bands in molecular crystals are suggested.",

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year = "1983",

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AU - Scharf, Benjamin

AU - Band, Yehuda B.

PY - 1983/6/17

Y1 - 1983/6/17

N2 - We consider the electronic transition between the split components of the excited electronic doublet of a dimer species when the monomer species have permanent dipole moments. We show that the transition moment is given in terms of the permanent dipole moments of the ground and excited states of the monomers. Extension to ionic dimers and transitions between exciton bands in molecular crystals are suggested.

AB - We consider the electronic transition between the split components of the excited electronic doublet of a dimer species when the monomer species have permanent dipole moments. We show that the transition moment is given in terms of the permanent dipole moments of the ground and excited states of the monomers. Extension to ionic dimers and transitions between exciton bands in molecular crystals are suggested.

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DO - 10.1016/0009-2614(83)87111-5

M3 - Article

AN - SCOPUS:48749145717

SN - 0009-2614

VL - 98

SP - 125

EP - 128

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Novel electronic transitions within excited doublets of dimers

Abstract

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