Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

M. L. Kaliya; S. B. Kogan; N. Froumin; M. Herskowitz

doi:10.1016/S1566-7367(02)00141-3

Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

M. L. Kaliya, S. B. Kogan, N. Froumin, M. Herskowitz

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Novel nitrogen contained catalyst CoN_x/Al₂O ₃ yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

Original language	English
Pages (from-to)	327-333
Number of pages	7
Journal	Catalysis Communications
Volume	3
Issue number	8
DOIs	https://doi.org/10.1016/S1566-7367(02)00141-3
State	Published - 1 Aug 2002

Keywords

Alumina
Cobalt phthalocyanine
Oxidative dehydrogenation
Propane
n-Butane

ASJC Scopus subject areas

Catalysis
General Chemistry
Process Chemistry and Technology

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10.1016/S1566-7367(02)00141-3

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title = "Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins",

abstract = "Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.",

keywords = "Alumina, Cobalt phthalocyanine, Oxidative dehydrogenation, Propane, n-Butane",

author = "Kaliya, {M. L.} and Kogan, {S. B.} and N. Froumin and M. Herskowitz",

year = "2002",

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doi = "10.1016/S1566-7367(02)00141-3",

language = "English",

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TY - JOUR

T1 - Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

AU - Kaliya, M. L.

AU - Kogan, S. B.

AU - Froumin, N.

AU - Herskowitz, M.

PY - 2002/8/1

Y1 - 2002/8/1

N2 - Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

AB - Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

KW - Alumina

KW - Cobalt phthalocyanine

KW - Oxidative dehydrogenation

KW - Propane

KW - n-Butane

UR - http://www.scopus.com/inward/record.url?scp=0011579434&partnerID=8YFLogxK

U2 - 10.1016/S1566-7367(02)00141-3

DO - 10.1016/S1566-7367(02)00141-3

M3 - Article

AN - SCOPUS:0011579434

SN - 1566-7367

VL - 3

SP - 327

EP - 333

JO - Catalysis Communications

JF - Catalysis Communications

IS - 8

ER -

Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

Abstract

Keywords

ASJC Scopus subject areas

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