Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

M. L. Kaliya; S. B. Kogan; N. Froumin; M. Herskowitz

doi:10.1016/S1566-7367(02)00141-3

Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

M. L. Kaliya
, S. B. Kogan
, N. Froumin
, M. Herskowitz

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Novel nitrogen contained catalyst CoN_x/Al₂O ₃ yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

Original language	English
Pages (from-to)	327-333
Number of pages	7
Journal	Catalysis Communications
Volume	3
Issue number	8
DOIs	https://doi.org/10.1016/S1566-7367(02)00141-3
State	Published - 1 Aug 2002

Keywords

Alumina
Cobalt phthalocyanine
Oxidative dehydrogenation
Propane
n-Butane

ASJC Scopus subject areas

Catalysis
General Chemistry
Process Chemistry and Technology

Access to Document

10.1016/S1566-7367(02)00141-3

Cite this

@article{0c4ac3a7349140a997ac9189667dace6,

title = "Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins",

abstract = "Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt\% yield of olefins at 82\% butane and 76. 7\% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.",

keywords = "Alumina, Cobalt phthalocyanine, Oxidative dehydrogenation, Propane, n-Butane",

author = "Kaliya, \{M. L.\} and Kogan, \{S. B.\} and N. Froumin and M. Herskowitz",

year = "2002",

month = aug,

day = "1",

doi = "10.1016/S1566-7367(02)00141-3",

language = "English",

volume = "3",

pages = "327--333",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

number = "8",

}

TY - JOUR

T1 - Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

AU - Kaliya, M. L.

AU - Kogan, S. B.

AU - Froumin, N.

AU - Herskowitz, M.

PY - 2002/8/1

Y1 - 2002/8/1

N2 - Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

AB - Novel nitrogen contained catalyst CoNx/Al2O 3 yielded high performance in the oxidative dehydrogenation of propane and n-butane. 47.6 and 37.4 wt% yield of olefins at 82% butane and 76. 7% propane conversion were measured at 600 °C. Ethylene and propylene were mainly formed at >400 °C via oxidative cracking of paraffins. XRD and XPS studies of the novel catalytic system indicate an essential modification of cobalt by nitrogen.

KW - Alumina

KW - Cobalt phthalocyanine

KW - Oxidative dehydrogenation

KW - Propane

KW - n-Butane

UR - https://www.scopus.com/pages/publications/0011579434

U2 - 10.1016/S1566-7367(02)00141-3

DO - 10.1016/S1566-7367(02)00141-3

M3 - Article

AN - SCOPUS:0011579434

SN - 1566-7367

VL - 3

SP - 327

EP - 333

JO - Catalysis Communications

JF - Catalysis Communications

IS - 8

ER -

Novel nitrogen containing heterogeneous catalysts for oxidative dehydrogenation of light paraffins

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this