Novel TTF Derivatives as Components for Conducting CT Complexes

J. Y. Becker; E. Aqad; J. Bernstein; A. Ellern; V. Khodorkovsky; T. Regev; L. Shahal; L. Shapiro; C.-S. Wang

doi:10.1007/978-94-015-8575-0_15

Novel TTF Derivatives as Components for Conducting CT Complexes

J. Y. Becker, E. Aqad, J. Bernstein, A. Ellern, V. Khodorkovsky, T. Regev, L. Shahal, L. Shapiro, C.-S. Wang

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

Original language	English
Title of host publication	Molecular Engineering for Advanced Materials
Editors	J. Y. Becher, Kjeld Schaumburg
Place of Publication	Dordrecht
Publisher	Springer Netherlands
Pages	277-293
Number of pages	17
Volume	456
ISBN (Print)	978-94-015-8575-0
DOIs	https://doi.org/10.1007/978-94-015-8575-0_15
State	Published - 1995

Publication series

Name	NATO ASI Series
Publisher	Kluwer Academic Publishers

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10.1007/978-94-015-8575-0_15

https://doi.org/10.1007/978-94-015-8575-0_15

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Becker, J. Y., Aqad, E., Bernstein, J., Ellern, A., Khodorkovsky, V., Regev, T., Shahal, L., Shapiro, L., & Wang, C-S. (1995). Novel TTF Derivatives as Components for Conducting CT Complexes. In J. Y. Becher, & K. Schaumburg (Eds.), Molecular Engineering for Advanced Materials (Vol. 456, pp. 277-293). (NATO ASI Series). Springer Netherlands. https://doi.org/10.1007/978-94-015-8575-0_15

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title = "Novel TTF Derivatives as Components for Conducting CT Complexes",

abstract = "Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669{\AA}) and Br...S (3.646{\AA}) interactions.",

author = "Becker, {J. Y.} and E. Aqad and J. Bernstein and A. Ellern and V. Khodorkovsky and T. Regev and L. Shahal and L. Shapiro and C.-S. Wang",

year = "1995",

doi = "10.1007/978-94-015-8575-0_15",

language = "English",

isbn = "978-94-015-8575-0",

volume = "456",

series = "NATO ASI Series",

publisher = "Springer Netherlands",

pages = "277--293",

editor = "Becher, {J. Y. } and Kjeld Schaumburg",

booktitle = "Molecular Engineering for Advanced Materials",

address = "Netherlands",

}

Becker, JY, Aqad, E, Bernstein, J, Ellern, A, Khodorkovsky, V, Regev, T, Shahal, L, Shapiro, L & Wang, C-S 1995, Novel TTF Derivatives as Components for Conducting CT Complexes. in JY Becher & K Schaumburg (eds), Molecular Engineering for Advanced Materials. vol. 456, NATO ASI Series, Springer Netherlands, Dordrecht, pp. 277-293. https://doi.org/10.1007/978-94-015-8575-0_15

TY - CHAP

T1 - Novel TTF Derivatives as Components for Conducting CT Complexes

AU - Becker, J. Y.

AU - Aqad, E.

AU - Bernstein, J.

AU - Ellern, A.

AU - Khodorkovsky, V.

AU - Regev, T.

AU - Shahal, L.

AU - Shapiro, L.

AU - Wang, C.-S.

PY - 1995

Y1 - 1995

N2 - Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

AB - Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

U2 - 10.1007/978-94-015-8575-0_15

DO - 10.1007/978-94-015-8575-0_15

M3 - Chapter

SN - 978-94-015-8575-0

VL - 456

T3 - NATO ASI Series

SP - 277

EP - 293

BT - Molecular Engineering for Advanced Materials

A2 - Becher, J. Y.

A2 - Schaumburg, Kjeld

PB - Springer Netherlands

CY - Dordrecht

ER -

Novel TTF Derivatives as Components for Conducting CT Complexes

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