Novel TTF Derivatives as Components for Conducting CT Complexes

J. Y. Becker; E. Aqad; J. Bernstein; A. Ellern; V. Khodorkovsky; T. Regev; L. Shahal; L. Shapiro; C.-S. Wang

doi:10.1007/978-94-015-8575-0_15

Novel TTF Derivatives as Components for Conducting CT Complexes

J. Y. Becker
, E. Aqad
, J. Bernstein
, A. Ellern
, V. Khodorkovsky
, T. Regev
, L. Shahal
, L. Shapiro
, C.-S. Wang

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

Original language	English
Title of host publication	Molecular Engineering for Advanced Materials
Editors	J. Y. Becher, Kjeld Schaumburg
Publisher	Springer, Dordrecht
Pages	277-293
Number of pages	17
ISBN (Electronic)	9789401585750
ISBN (Print)	9780792333470
DOIs	https://doi.org/10.1007/978-94-015-8575-0_15
State	Published - Jan 1995

Access to Document

10.1007/978-94-015-8575-0_15

Cite this

@inbook{487f63651e0b442bbc393c104a7b1c0a,

title = "Novel TTF Derivatives as Components for Conducting CT Complexes",

abstract = "Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669{\AA}) and Br...S (3.646{\AA}) interactions.",

author = "Becker, \{J. Y.\} and E. Aqad and J. Bernstein and A. Ellern and V. Khodorkovsky and T. Regev and L. Shahal and L. Shapiro and C.-S. Wang",

year = "1995",

month = jan,

doi = "10.1007/978-94-015-8575-0\_15",

language = "English",

isbn = "9780792333470",

pages = "277--293",

editor = "Becher, \{J. Y. \} and Kjeld Schaumburg",

booktitle = "Molecular Engineering for Advanced Materials",

publisher = "Springer, Dordrecht",

}

TY - CHAP

T1 - Novel TTF Derivatives as Components for Conducting CT Complexes

AU - Becker, J. Y.

AU - Aqad, E.

AU - Bernstein, J.

AU - Ellern, A.

AU - Khodorkovsky, V.

AU - Regev, T.

AU - Shahal, L.

AU - Shapiro, L.

AU - Wang, C.-S.

PY - 1995/1

Y1 - 1995/1

N2 - Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

AB - Halogenated TTF derivatives, especially iodinated ones, are important compounds as intermediates for further TTF derivatization, as well as for their intrinsic value as donors with an increased tendency to participate in intermolecular interactions compared to TTF, in the charge transfer (CT) complexes and ion-radical salts derived from them1. Our previous work has shown that stepwise bromination of lithiated TTF can give rise exclusively to 2,3-dibromo-TTF in moderate yields2, out of the three possible dibromo-TTF isomers. The stacking mode (Figure 1) shows both Br...Br (3.669Å) and Br...S (3.646Å) interactions.

U2 - 10.1007/978-94-015-8575-0_15

DO - 10.1007/978-94-015-8575-0_15

M3 - Chapter

SN - 9780792333470

SP - 277

EP - 293

BT - Molecular Engineering for Advanced Materials

A2 - Becher, J. Y.

A2 - Schaumburg, Kjeld

PB - Springer, Dordrecht

ER -

Novel TTF Derivatives as Components for Conducting CT Complexes

Abstract

Access to Document

Fingerprint

Cite this