Octakis(3-propylammonium) octadecaiodopentaplumbate(II): A new layered stucture based on layered perovskites

David G. Billing; Andreas Lemmerer

doi:10.1107/S0108270106014417

Octakis(3-propylammonium) octadecaiodopentaplumbate(II): A new layered stucture based on layered perovskites

David G. Billing
, Andreas Lemmerer

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The title compound, (C₃H₁₀N)₈[Pb ₅I₁₈], crystallizes as an inorganic-organic hybrid. As such, the structure consists of two-dimensional sheets of corner- and face-sharing [PbI₆]^4- octahedra, separated by layers of 3-propylammonium cations, which hydrogen bond to the I atoms. The asymmetric unit contains six independent Pb atoms; four are on general positions and the other two are on special positions, viz. a centre of inversion and a twofold axis. The inorganic sheets show a never before seen motif.

Original language	English
Pages (from-to)	m238-m240
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	6
DOIs	https://doi.org/10.1107/S0108270106014417
State	Published - 1 Jun 2006
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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10.1107/S0108270106014417

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title = "Octakis(3-propylammonium) octadecaiodopentaplumbate(II): A new layered stucture based on layered perovskites",

abstract = "The title compound, (C3H10N)8[Pb 5I18], crystallizes as an inorganic-organic hybrid. As such, the structure consists of two-dimensional sheets of corner- and face-sharing [PbI6]4- octahedra, separated by layers of 3-propylammonium cations, which hydrogen bond to the I atoms. The asymmetric unit contains six independent Pb atoms; four are on general positions and the other two are on special positions, viz. a centre of inversion and a twofold axis. The inorganic sheets show a never before seen motif.",

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year = "2006",

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T1 - Octakis(3-propylammonium) octadecaiodopentaplumbate(II)

T2 - A new layered stucture based on layered perovskites

AU - Billing, David G.

AU - Lemmerer, Andreas

PY - 2006/6/1

Y1 - 2006/6/1

N2 - The title compound, (C3H10N)8[Pb 5I18], crystallizes as an inorganic-organic hybrid. As such, the structure consists of two-dimensional sheets of corner- and face-sharing [PbI6]4- octahedra, separated by layers of 3-propylammonium cations, which hydrogen bond to the I atoms. The asymmetric unit contains six independent Pb atoms; four are on general positions and the other two are on special positions, viz. a centre of inversion and a twofold axis. The inorganic sheets show a never before seen motif.

AB - The title compound, (C3H10N)8[Pb 5I18], crystallizes as an inorganic-organic hybrid. As such, the structure consists of two-dimensional sheets of corner- and face-sharing [PbI6]4- octahedra, separated by layers of 3-propylammonium cations, which hydrogen bond to the I atoms. The asymmetric unit contains six independent Pb atoms; four are on general positions and the other two are on special positions, viz. a centre of inversion and a twofold axis. The inorganic sheets show a never before seen motif.

UR - https://www.scopus.com/pages/publications/33745135078

U2 - 10.1107/S0108270106014417

DO - 10.1107/S0108270106014417

M3 - Article

AN - SCOPUS:33745135078

SN - 0108-2701

VL - 62

SP - m238-m240

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

Octakis(3-propylammonium) octadecaiodopentaplumbate(II): A new layered stucture based on layered perovskites

Abstract

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