On the importance of the average logarithmic energy loss in connection with the yields of hot halogen reactions

Z. B. Alfassi; S. Amiel

doi:10.1016/0009-2614(71)80074-X

On the importance of the average logarithmic energy loss in connection with the yields of hot halogen reactions

Z. B. Alfassi, S. Amiel

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The average logarithmic energy losses of hot halogen atoms in collisions with methane and methyl halides are substantially different. The difference amounts to a factor of about 4 for Cl and 10 for Br. This means that only the reactivity integrals, or the yields of displacement reactions by hot atoms in highly moderated systems, can serve as indicators of the actual cross sections of such reactions, while the yield in undermoderated systems may be misleading.

Original language	English
Pages (from-to)	487-488
Number of pages	2
Journal	Chemical Physics Letters
Volume	8
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(71)80074-X
State	Published - 15 Mar 1971
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/0009-2614(71)80074-X

Cite this

@article{ae4dc20e79d84b28bafe9711d8ebc742,

title = "On the importance of the average logarithmic energy loss in connection with the yields of hot halogen reactions",

abstract = "The average logarithmic energy losses of hot halogen atoms in collisions with methane and methyl halides are substantially different. The difference amounts to a factor of about 4 for Cl and 10 for Br. This means that only the reactivity integrals, or the yields of displacement reactions by hot atoms in highly moderated systems, can serve as indicators of the actual cross sections of such reactions, while the yield in undermoderated systems may be misleading.",

author = "Alfassi, {Z. B.} and S. Amiel",

year = "1971",

month = mar,

day = "15",

doi = "10.1016/0009-2614(71)80074-X",

language = "English",

volume = "8",

pages = "487--488",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - On the importance of the average logarithmic energy loss in connection with the yields of hot halogen reactions

AU - Alfassi, Z. B.

AU - Amiel, S.

PY - 1971/3/15

Y1 - 1971/3/15

N2 - The average logarithmic energy losses of hot halogen atoms in collisions with methane and methyl halides are substantially different. The difference amounts to a factor of about 4 for Cl and 10 for Br. This means that only the reactivity integrals, or the yields of displacement reactions by hot atoms in highly moderated systems, can serve as indicators of the actual cross sections of such reactions, while the yield in undermoderated systems may be misleading.

AB - The average logarithmic energy losses of hot halogen atoms in collisions with methane and methyl halides are substantially different. The difference amounts to a factor of about 4 for Cl and 10 for Br. This means that only the reactivity integrals, or the yields of displacement reactions by hot atoms in highly moderated systems, can serve as indicators of the actual cross sections of such reactions, while the yield in undermoderated systems may be misleading.

UR - http://www.scopus.com/inward/record.url?scp=49649151446&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(71)80074-X

DO - 10.1016/0009-2614(71)80074-X

M3 - Article

AN - SCOPUS:49649151446

SN - 0009-2614

VL - 8

SP - 487

EP - 488

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

On the importance of the average logarithmic energy loss in connection with the yields of hot halogen reactions

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this